RSM-based co-gasification of palm oil decanter cake and sugarcane bagasse: Syngas production and biochar characteristics
Journal
Biomass and Bioenergy
ISSN
0961-9534
Date Issued
2024-12
Author(s)
Kunmi Joshua Abioye
Noorfidza Yub Harun
Mohammad Yusuf
Hesam Kamyab
Joshua O. Ighalo
Wael Almusattar
Joshua Olanrewaju Olaoye
Adesoji Matthew Olaniyan
M. Atif
Ashok Kumar
Chander Prakash
Shilpa Pande
Abstract
The production of syngas (CO + H2) and biochar from biomass waste co-gasification promotes sustainable energy while addressing environmental remediation challenges. This study investigates the co-gasification of palm oil decanter cake (PODC) and sugarcane bagasse (SB) to optimize syngas production and obtain biochar in a fixed bed horizontal tube furnace reactor.
Operating variables, including temperature (700–900 °C), biomass ratio (30–70 wt%), and particle size (0.25–2 mm), were optimized using Response Surface Methodology with the Box-Behnken design. Characterization analyses including Brunauer-Emmett-Teller (BET), Fourier Transformed Infrared (FTIR), and Field Emission Scanning Electron Microscopic (FESEM) analyses were conducted on the biochar.
The optimal conditions yielded a syngas volume of 41.5 vol% and a biochar of 0.3 wt%, achieved at 900 °C temperature, 42 wt% PODC biomass ratio, and 2 mm particle size. BET analysis revealed a mesoporous structure biochar with surface area of 398.55 m2/g, pore volume of 0.13 cm3/g, and pore diameter of 6.49 nm.
FTIR analysis indicated the presence of hydroxyl groups, carbonyl groups, aromatic compounds, and hydrocarbon structures. FESEM analysis showed well-defined pore structures on the biochar surface, with EDX analysis confirming a dominant carbon content of 83.32 wt%.
These findings substantially enhance sustainable approaches in energy production, agriculture, and wastewater treatment, while effectively tackling environmental issues associated with biomass waste.
Operating variables, including temperature (700–900 °C), biomass ratio (30–70 wt%), and particle size (0.25–2 mm), were optimized using Response Surface Methodology with the Box-Behnken design. Characterization analyses including Brunauer-Emmett-Teller (BET), Fourier Transformed Infrared (FTIR), and Field Emission Scanning Electron Microscopic (FESEM) analyses were conducted on the biochar.
The optimal conditions yielded a syngas volume of 41.5 vol% and a biochar of 0.3 wt%, achieved at 900 °C temperature, 42 wt% PODC biomass ratio, and 2 mm particle size. BET analysis revealed a mesoporous structure biochar with surface area of 398.55 m2/g, pore volume of 0.13 cm3/g, and pore diameter of 6.49 nm.
FTIR analysis indicated the presence of hydroxyl groups, carbonyl groups, aromatic compounds, and hydrocarbon structures. FESEM analysis showed well-defined pore structures on the biochar surface, with EDX analysis confirming a dominant carbon content of 83.32 wt%.
These findings substantially enhance sustainable approaches in energy production, agriculture, and wastewater treatment, while effectively tackling environmental issues associated with biomass waste.