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    Sustainable valorization of leachate at Lakhodair landfill, Lahore: An integrated life cycle environmental and economic assessment of biogas production
    (Elsevier BV, 2026-02)
    Mehak Saghir
    ;
    Aqsa Ayub
    ;
    Abdul-Sattar Nizami
    ;
    Mujtaba Baqar
    ;
    HESAM, KAMYAB  
    The rapid growth of the human population has led to a significant increase in municipal solid waste (MSW), which is projected to reach 2.2 billion tons per year by the end of 2025. This has caused a problem with landfill leachate. Biogas production from landfill leachate offers a sustainable solution to mitigate environmental issues, including greenhouse gas emissions and groundwater contamination, while recovering clean energy and valuable resources from waste. This study simulates and assesses the environmental and economic benefits of biogas production from leachate using a life-cycle assessment (LCA) framework. The environmental impacts were evaluated using the LCA methodology and the ReCiPe 2016 midpoint (H) approach, which comprises 18 different environmental categories. Midpoint results revealed that terrestrial eco-toxicity, climate change, and fossil depletion were the main impact categories that potentially contributed to 3.63 × 101 kg 1,4-DB eq., 5.37 × 102 kg CO2 eq., and 1.83 × 101 kg oil eq., respectively, for 1 m3 of biogas production. Scenario modeling was performed by replacing the power source with a solar cell rather than grid electricity. Shifting to solar energy resulted in a GWP of 535 kg CO2 equivalent and an FDP of 18 kg oil equivalent per m3 of biogas production. Sensitivity and uncertainty analyses were conducted to evaluate environmental performance, with electricity and other inputs identified as key drivers of environmental impact. Financial analysis of 1300 m3 biogas plant reveals strong economic performance, with annual revenue of USD 651,495.98 and operational expenditures of USD 541,352.98. The project's profitability is underscored by a 2-year payback period, a positive NPV of 6,372,112.71, and an IRR of 34.53 %. While external costs, including USD 15.75 per m3 for emissions management, are notable, the environmental benefits of reduced leachate problems and electricity generation support the project's viability. This study provides policymakers, waste management practitioners, and stakeholders with valuable insights into reducing environmental impacts while increasing resource recovery from waste streams. This research aligns with several United Nations Sustainable Development Goals (SDGs), including SDG 6, 7, 11, 14, and 15, by advancing clean energy, promoting economic growth, fostering sustainable communities, and enhancing environmental protection.
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    Characterisation of synthesised trimetallic nanoparticles and its influence on anaerobic digestion of palm oil mill effluent
    (Elsevier BV, 2024-01)
    Pramod Jadhav
    ;
    Santhana Krishnan
    ;
    Hesam Kamyab
    ;
    Zaied bin Khalid
    ;
    Prakash Bhuyar
    The augmentation of biogas production can be achieved by incorporating metallic nanoparticles as additives within anaerobic digestion. The objective of this current study is to examine the synthesis of Fe–Ni–Zn and Fe–Co–Zn trimetallic nanoparticles using the co-precipitation technique and assess its impact on anaerobic digestion using palm oil mill effluent (POME) as carbon source. The structural morphology and size of the synthesised trimetallic nanoparticles were analysed using a range of characterization techniques, such as X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), and Energy-dispersive X-ray spectroscopy (EDX). The average size of Fe–Ni–Zn and Fe–Co–Zn were 19–25.5 nm and 19.1–30.5 nm respectively. Further, investigation focused on examining the diverse concentrations of trimetallic nanoparticles, ranging from 0 to 50 mgL−1. The biogas production increased by 55.55% and 60.11% with Fe–Ni–Zn and Fe–Co–Zn trimetallic nanoparticles at 40 mgL−1 and 20 mgL−1, respectively. Moreover, the lowest biogas of 11.11% and 38.11% were found with 10 mgL-1 of Fe–Ni–Zn and Fe–Co–Zn trimetallic nanoparticles. The findings of this study indicated that the trimetallic nanoparticles exhibited interactions with anaerobes, thereby enhancing the degradation process of palm oil mill effluent (POME) and biogas production. The study underscores the potential efficacy of trimetallic nanoparticles as a viable supplement for the promotion of sustainable biogas generation.