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Treatment of metronidazole in wastewater by nano zero-valent iron/copper slag nanocomposite
(Elsevier BV, 2025-10)
Mohammadhashem Shahbazi
;
Samad Sabbaghi
;
Naghmeh Sadat Mirbagheri
;
Rahmatallah Saboori
;
Jeyran Mirhosseininia
In the last two decades, special concern has been focused on certain drugs such as Metronidazole (MNZ) owing to their potential carcinogenic and mutagenic properties. In the current study, nano zero-valent iron (nZVI) combined with Copper Slag was utilized for the adsorption of MNZ from an aqueous environment. The proper distribution of nZVI was confirmed by surface morphology analysis using FESEM. In addition, the incorporation of nZVI into Copper Slag led to an approximate 82% increase in BET surface area and a more than 20% rise in iron content according to the EDX result, which together contributed to a 90% improvement in MNZ removal efficiency from aqueous solutions. The optimum conditions (initial MNZ concentration of 27.9 mg/L, adsorbent quantity of 6.8 g/L, contact time of 35.5 min, and an initial pH of 5.04) were attained, demonstrating excellent adsorbent removal efficiency through running the CCD design. The Langmuir isotherm accurately described MNZ adsorption on nZVI/Copper Slag, and kinetic modeling showed that the experimental data fit well with the pseudo-first-order. The adsorption of MNZ onto the adsorbent is spontaneous and exothermic, with ∆G° < 0 and ∆S° < 0, indicating thermodynamic favorability and increased order at the solid–solution interface. Furthermore, it indicated excellent reusability and regeneration performance over six consecutive cycles.
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Process development of guava leaves with alkali in removal of zinc ions from synthetic wastewater
(Elsevier BV, 2023-12)
Chanda Sireesha
;
Kaliannan Durairaj
;
Balamuralikrishnan Balasubramanian
;
Shanmugam Sumithra
;
Rajendran Subha
Background: This research investigation delves into the efficient removal of zinc ions from synthetic wastewater through the utilization of KOH treated guava leaves as an adsorbent. The study employs advanced analytical techniques including SEM, FTIR, XRD, and BET analysis to characterize the physicochemical properties of the treated guava leaves. The research extensively explores the impact of various experimental factors on the adsorption process, encompassing agitation time, adsorbent dosage, pH levels, and desorption, to identify optimal conditions for maximum Zn (II) ion removal. Methods: The research methodology involves subjecting guava leaves treated with KOH to thorough analysis using SEM, FTIR, XRD, and BET techniques to gain insights into their physical and chemical attributes. The study systematically investigates the adsorption process by manipulating crucial parameters such as agitation time, adsorbent dosage, and pH levels. Different isotherm models including Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich are applied to comprehend the adsorption mechanism. Additionally, kinetic calculations are performed, leading to the determination that the pseudo-second-order model best fits the removal of zinc metal. Significant Findings: The research uncovers essential findings regarding the efficacy of KOH treated guava leaves as an adsorbent for zinc ions. Optimum conditions are pH 3 are identified, an adsorbent dosage of 100 mg/L, and an equilibrium period of 20 min, resulting in peak efficiency of the adsorption process. The study reveals an adsorption capacity of 14.5 mg/g for the studied metal, emphasizing the potential of KOH treated guava leaves as an efficient adsorbent for zinc ions. The adsorption capacity is 5.1 mg/g for the untreated guava leaves. The findings underscore the feasibility of utilizing this eco-friendly approach for wastewater management, thereby contributing to environmental remediation and pollution control efforts. The research highlights the practical application of KOH treated guava leaves in wastewater treatment processes, advocating for further exploration and optimization of this sustainable solution to address heavy metal contamination and promote greener technologies for water purification and waste management.
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Metformin-modified polyethersulfone magnetic microbeads for effective arsenic removal from apatite soil leachate water
(Elsevier BV, 2024-01)
Shakila Kalami
;
Ekaterina Diakina
;
Roya Noorbakhsh
;
Sina Sheidaei
;
Shahabaldin Rezania
Arsenic is the hazardous species and still is the global challenge in water treatment. Apatite soil is highly rich in arsenic species, and its mining presents various environmental issues. In this study, novel magnetic microbeads as adsorbent were developed for the elimination of hazardous arsenic ions from apatite soil's aqueous leachate before discharging into environment. The microbeads were fabricated with metformin polyether sulfone after being doped with zero-valent iron (Met-PES/ZVI). The microbeads were characterized using various techniques, including FTIR, XRD, SEM-EDX, VSM, and zeta potential analysis. The developed adsorbent demonstrated a significant elimination in arsenic in aqueous leachate, achieving 82.39% removal after 30 min of contact time, which further increased to 90% after 180 min of shaking. The kinetic analysis revealed that the pseudo-second-order model best represented the adsorption process. The intra-particle diffusion model indicated that the adsorption occurred in two steps. The Langmuir model (R2 = 0.991), with a maximum adsorption capacity of 188.679 mg g−1, was discovered to be the best fit for the experimental data as compared Freundlich model (R2 = 0.981). According to the thermodynamic outcome (ΔG < −20 kJ/mol), the adsorption process was spontaneous and involved physisorption. These findings demonstrate the potential of magnetic Met-PES/ZVI microbeads as an efficient adsorbent for the removal of arsenic from apatite soil aqueous leachate.

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